The rod-shaped secondary building unit (ROD-SBU) and organic ligands assembled ROD-MOF is a characteristic structure that the research group has been studying. Due to the one-dimensional chain arrangement of metal ions in ROD-MOF and the coordination with ligands, the framework material usually has pore distribution in the same direction. Materials with good pores are usually conducive to mass transfer, which is not only beneficial for gas adsorption but also for mass transfer in catalytic reactions. In this chapter, a Ag-ROD framework material composed of dual-core silver rod-shaped secondary building units and bidentate triazole ligands was synthesized, and its application effect in the field of electrocatalytic CO2RR was studied.


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