This article investigates the photocatalytic CO2RR and electrocatalytic CO2RR of two types of materials through experiments. Specifically, the impact of efficient photoinduced charge transfer on photocatalytic CO2RR is explored by constructing electron donor-acceptor (D-A) materials using porphyrin-based metal-organic frameworks as composite affinity points. Additionally, the use of rod-shaped metal secondary building units is synthesized to study whether rod-shaped metal elements are advantageous for electrocatalytic CO2RR.


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