Rewrite This article investigates the photocatalytic CO2RR and electrocatalytic CO2RR of two types of materials through experiments Specifically the impact of efficient photoinduced charge transfer on

This study delves into the photocatalytic and electrocatalytic CO2 reduction reactions of two distinct materials via experimental analysis. More specifically, the investigation focuses on the role of efficient photoinduced charge transfer in photocatalytic CO2RR, utilizing electron donor-acceptor (D-A) materials composed of porphyrin-based metal-organic frameworks as composite affinity points. Furthermore, the synthesis of rod-shaped metal secondary building units is implemented to assess the potential advantages of rod-shaped metal elements in electrocatalytic CO2RR.